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Proceedings Paper

Volume holographic recording in multicomponent photopolymers with hyperbranched polymers as organic nanoparticles
Author(s): Yasuo Tomita; Kouji Furushima; Yutaka Endoh; Motohiko Hidaka; Kentaro Ohmori; Katsumi Chikama
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Paper Abstract

We describe the diffraction properties of organic nanoparticle-dispersed photopolymers in which hyperbranched polymers (HBPs) act as transporting organic nanoparticles that increase the refractive-index contrast of a hologram. We prepared HBPs by the living radical vinyl polymerization of inimers under ultraviolet-light illumination. Such synthesized HBPs are easy to disperse into monomers without any aggregation, so that samples with good optical quality are available. We investigate the role of HBPs in the recording process for two different types of photopolymers capable of radical polymerization and cationic ring-opening polymerization. We also evaluate the effect of HBP dispersion on recording sensitivities and polymerization shrinkage.

Paper Details

Date Published: 25 April 2006
PDF: 10 pages
Proc. SPIE 6187, Photon Management II, 618702 (25 April 2006); doi: 10.1117/12.663206
Show Author Affiliations
Yasuo Tomita, Univ. of Electro-Communications (Japan)
Kouji Furushima, Univ. of Electro-Communications (Japan)
Yutaka Endoh, Univ. of Electro-Communications (Japan)
Motohiko Hidaka, Nissan Chemical Industries, Ltd. (Japan)
Kentaro Ohmori, Nissan Chemical Industries, Ltd. (Japan)
Katsumi Chikama, Nissan Chemical Industries, Ltd. (Japan)


Published in SPIE Proceedings Vol. 6187:
Photon Management II
John T. Sheridan; Frank Wyrowski, Editor(s)

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