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Proceedings Paper

Characterization of cobalt doped ZnSe and ZnS crystals as saturable absorbers for alexandrite lasers
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Paper Abstract

Cobalt doped ZnSe and ZnS crystals have been studied to determine their effectiveness for passive Q-switching for 700-800nm spectral range (Alexandrite laser). Samples were prepared using Bridgeman technique for single-step growth of Co doped crystals as well as after growth thermal diffusion of Co in undoped crystals. ZnS:Co:Cr crystals, which have been produced using the Bridgeman technique, show maximum initial absorption coefficients of 17 cm-1 at 725nm. Experimental results are reported on effective thermal diffusion of Co2+ in ZnSe and ZnS polycrystals and thermal diffusion constants of cobalt ions in ZnSe and ZnS are estimated. The nonlinear saturation properties of cobalt doped ZnSe and ZnS crystals have been investigated experimentally. The induced transparency measurements were performed using electro-optically Q-switched, alexandrite laser radiation at 731, 741, and 778 nm with a pulse duration of about 70 ns. The induced transmission measurements were analyzed using a four-level absorber model and the absorption cross sections have been estimated at both 731nm and 741nm to be 9.5 × 10-18 cm2 and 8.2 × 10-18 cm2, respectively. Absorption cross sections calculated from saturation measurements at 4A24T1(4P) transition are in agreement with results earlier reported for mid-infrared spectral region 4A24T2 of Co2+ ions. The described Co-doped crystals are very promising as passive Q-switches for alexandrite laser resonators. Co2+ centers feature high cross section of saturation and their absorption bands are nicely matched to the spectral emission of the tunable alexandrite laser. An efficient ZnS:Co:Cr passive Q-switching of the alexandrite laser cavity was realized with output energy of 15 mJ and 50 ns pulse duration.

Paper Details

Date Published: 28 February 2006
PDF: 10 pages
Proc. SPIE 6100, Solid State Lasers XV: Technology and Devices, 61000U (28 February 2006); doi: 10.1117/12.646666
Show Author Affiliations
Robert A. Sims, The Univ. of Alabama at Birmingham (United States)
Samford Univ. (United States)
John Kernal, The Univ. of Alabama at Birmingham (United States)
Vladimir V. Fedorov, The Univ. of Alabama at Birmingham (United States)
Sergey B. Mirov, The Univ. of Alabama at Birmingham (United States)


Published in SPIE Proceedings Vol. 6100:
Solid State Lasers XV: Technology and Devices
Hanna J. Hoffman; Ramesh K. Shori, Editor(s)

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