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Proceedings Paper

Surface-immobilized polyampholytic silver nanoparticles for SERS detection of cations and anions in aqueous solutions
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Paper Abstract

A new procedure was used for the preparation of stable silver colloids by reduction of silver nitrate with (N (2 hydroxyethyl) piperazine N'-2 ethanesulfonic acid (HEPES). The nanoparticle size and the surface charge could be tuned by changing the initial pH of a HEPES solution. Rhodamine 6G and NaSCN were used respectively as model cationic and anionic analytes to study the effect of surface charge of the silver colloids on detection sensitivity. The silver colloids exhibit SERS activity comparable to those obtained by the popular Lee-Meisel approach. The combination of the high SERS sensitivity and the ability to control the nature of surface charge renders HEPES-reduced polyampholytic silver colloids a potentially powerful platform for sensing and detection of both cations and anions in aqueous solutions.

Paper Details

Date Published: 17 November 2005
PDF: 8 pages
Proc. SPIE 6008, Nanosensing: Materials and Devices II, 600808 (17 November 2005); doi: 10.1117/12.630669
Show Author Affiliations
Siliu Tan, Stevens Institute of Technology (United States)
Denis Pristinski, Stevens Institute of Technology (United States)
Svetlana Sukhishvili, Stevens Institute of Technology (United States)
Henry Du, Stevens Institute of Technology (United States)


Published in SPIE Proceedings Vol. 6008:
Nanosensing: Materials and Devices II
M. Saif Islam; Achyut K. Dutta, Editor(s)

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