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Proceedings Paper

Reaction intermediates in organometallic chemistry studied by time-resolved infrared spectral techniques
Author(s): Peter C. Ford; John A. Di Benedetto; David W. Ryba; Simon T. Belt
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Paper Abstract

Applications of flash photolysis with time resolved infrared (TRIR) detection techniques to kinetics investigations of reactive organometallic intermediates are described. The apparatus used a XeCl excimer laser as the pump source and lead salt diode lasers as probe sources with an overall tuning range from 1550 to 2200 cm1. For illustration, flash photolysis studies of some ruthenium and iron carbonyl complexes relevant to the catalytic activation of carbon monoxide and of other small molecules will be reviewed.

Paper Details

Date Published: 14 May 1992
PDF: 8 pages
Proc. SPIE 1636, Applied Spectroscopy in Materials Science II, (14 May 1992); doi: 10.1117/12.59289
Show Author Affiliations
Peter C. Ford, Univ. of California/Santa Barbara (United States)
John A. Di Benedetto, Univ. of California/Santa Barbara (United States)
David W. Ryba, Univ. of California/Santa Barbara (United States)
Simon T. Belt, Univ. of California/Santa Barbara (United States)


Published in SPIE Proceedings Vol. 1636:
Applied Spectroscopy in Materials Science II
William G. Golden, Editor(s)

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