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Proceedings Paper

Resonance Raman study of Zn-porphyrin pi-anions
Author(s): G. P. Gurinovich; Sergei G. Kruglik; Vladimir V. Kvach; S. N. Terekhov
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Paper Abstract

The first attempts to obtain resonance Raman (RR) spectra of metalloporphyrin ir-anions1 and the works that followed24 showed that RR spectroscopy could be regarded as a method for studying the electronic structure of these compounds. This paper deals with the RR study of ir-anions of Zn-porphyrin complexes. We focus on the analysis of changes in the electronic structure, force field and ir-orders of bonds which take place in the porphyrin cycle as a result of successive single-electron reduction: from monoanion to tetraanion.

Paper Details

Date Published: 1 May 1991
PDF: 3 pages
Proc. SPIE 1403, Laser Applications in Life Sciences, (1 May 1991); doi: 10.1117/12.57271
Show Author Affiliations
G. P. Gurinovich, B. I. Stepanov Institute of Physics (Belarus)
Sergei G. Kruglik, B. I. Stepanov Institute of Physics (Belarus)
Vladimir V. Kvach, B. I. Stepanov Institute of Physics (Belarus)
S. N. Terekhov, B. I. Stepanov Institute of Physics (Belarus)

Published in SPIE Proceedings Vol. 1403:
Laser Applications in Life Sciences
Sergei A. Akhmanov; Marina Yu. Poroshina, Editor(s)

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