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Proceedings Paper

Conformational probes in glassy polymers: free volume and relaxation transitions (FT-IR spectroscopy)
Author(s): D. I. Kamalova; S. A. Petrova; A. B. Remizov
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Paper Abstract

The method of conformational probes has been developed. The conformational mobility of probes introduced into poly(methyl methacrylate) (PMMA) and having different sizes of rotational fragments (Vp) has been investigated. There is a correlation between the freezing temperature of probe conformational transitions (Tf) and Vp. These data have been considered within the frameworks of the free volume theory and the relaxational transitions. Conformational mobility of probes in poly(vinyl trimethylsilane) (PVTMS) and poly(trimethylsilyl propyne) (PTMSP) with a large free volume fraction has been studied.

Paper Details

Date Published: 20 July 2004
PDF: 6 pages
Proc. SPIE 5507, XVI International Conference on Spectroscopy of Molecules and Crystals, (20 July 2004); doi: 10.1117/12.570006
Show Author Affiliations
D. I. Kamalova, Kazan State Univ. (Russia)
S. A. Petrova, Kazan State Technological Univ. (Russia)
A. B. Remizov, Kazan State Technological Univ. (Russia)


Published in SPIE Proceedings Vol. 5507:
XVI International Conference on Spectroscopy of Molecules and Crystals
Galyna O. Puchkovska; Tatiana A. Gavrilko; Olexandr I. Lizengevich, Editor(s)

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