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Proceedings Paper

Intrazeolite carbonyl metal chemistry: in-situ diffuse-reflectance infrared Fourier transform investigation
Author(s): H. Boulet-Desgrousilliers; C. P. Bremard; Christophe Depecker; P. Legrand
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Paper Abstract

Diffuse Reflectance Infrared Fourier Transform Spectroscopic (DRIFTS) investigations indicate that under thermal activation, the coadsorption, by vapor-phase loading of benzene in the Na85%/X faujasite-type zeolite leads to the grafted Mo(CO3 moiety, whereas (n6-C6H6) Mo(CO)3 is obtained in Na55Y; no reaction is observed in the dealuminated Y* zeolite before the desorption on both benzene and Mo(CO)6.

Paper Details

Date Published: 1 March 1992
PDF: 2 pages
Proc. SPIE 1575, 8th Intl Conf on Fourier Transform Spectroscopy, (1 March 1992); doi: 10.1117/12.56369
Show Author Affiliations
H. Boulet-Desgrousilliers, Univ. des Sciences et Techniques de Lille Flandres (France)
C. P. Bremard, Univ. des Sciences et Techniques de Lille Flandres (France)
Christophe Depecker, Univ. des Sciences et Techniques de Lille Flandres (France)
P. Legrand, Univ. des Sciences et Techniques de Lille Flandres (France)


Published in SPIE Proceedings Vol. 1575:
8th Intl Conf on Fourier Transform Spectroscopy

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