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Proceedings Paper

Site structure in the electronic and IR spectra of porphyrin
Author(s): J. G. Radziszewski; Josef Michl; Jacek Waluk
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Paper Abstract

The spectra of porphyrin isolated in low temperature noble gas and nitrogen matrices reveal a multiplet structure consisting of pairs of sites (A and B) which may be interconverted as a result of photo-induced double proton transfer. Single-site spectra are obtained for IR, electronic absorption, fluorescence and phosphorescence. Analysis of different magnitudes and signs of site-splittings in the IR spectra may be helpful for vibrational assignments.

Paper Details

Date Published: 1 March 1992
PDF: 2 pages
Proc. SPIE 1575, 8th Intl Conf on Fourier Transform Spectroscopy, (1 March 1992); doi: 10.1117/12.56291
Show Author Affiliations
J. G. Radziszewski, Univ. of California/Irvine (United States)
Josef Michl, Univ. of Colorado/Boulder (United States)
Jacek Waluk, Institute of Physical Chemistry (Poland)

Published in SPIE Proceedings Vol. 1575:
8th Intl Conf on Fourier Transform Spectroscopy
Herbert Michael Heise; Ernst Heiner Korte; Heinz W. Siesler, Editor(s)

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