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Proceedings Paper

Nanocomposite solar cells: influence of particle concentration, size, and shape on the device performance
Author(s): Chung Yin Kwong; Aleksandra B. Djurisic; Po Ching Chui; Wai Kin Chan
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Paper Abstract

Solar cells based on poly(3-hexylthiophene) (P3HT) :TiO2 nanocomposite films were investigated. We studied the influence of the nanoparticle concentrations and different nanostructures (spherical particles with size ~5 nm and ~20-40 nm, and rods with diameter ~10 nm and length ~40 nm) on the performance of the nanocomposite solar cells. PL quenching and improved external quantum efficiency (EQE) was observed for all the nanocomposite devices compared to that of pristine P3HT solar cells. However, TiO2 (~5 nm spheres) and TiO2 rods showed only small improvement in EQE. The small improvement for the 5 nm TiO2 spheres was attributed to the lack of connectivity of nanoparticles for electron conduction. Therefore, the charge collection efficiency was limited. For TiO2 rods, the tendency of the rods to lie in the plane of substrates also limited the charge conduction and collection in the direction perpendicular to the substrates. Therefore, the improvement of the devices made by these nanoparticles was limited. For TiO2 (20-40 nm spheres) with optimal concentration, external quantum efficiency up to 15% and AM1 power conversion efficiency of 0.42% were obtained. The improvement in the efficiency was related to the improved morphology of the film and was attributed to the formation of percolation paths of TiO2 for electron conduction.

Paper Details

Date Published: 3 November 2004
PDF: 8 pages
Proc. SPIE 5520, Organic Photovoltaics V, (3 November 2004); doi: 10.1117/12.558683
Show Author Affiliations
Chung Yin Kwong, Univ. of Hong Kong (Hong Kong China)
Aleksandra B. Djurisic, Univ. of Hong Kong (Hong Kong China)
Po Ching Chui, Univ. of Hong Kong (Hong Kong China)
Wai Kin Chan, Univ. of Hong Kong (Hong Kong China)

Published in SPIE Proceedings Vol. 5520:
Organic Photovoltaics V
Zakya H. Kafafi; Paul A. Lane, Editor(s)

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