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Proceedings Paper

Influence of the intramolecular interactions on intermolecular potential matrix elements
Author(s): Valentina N. Stroinova; Yurii I. Tyurin; Alexander D. Bykov; Vladimir M. Mikhailov
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Paper Abstract

General analytical expressions for non-diagonal matrix elements of intermolecular potential operator are found using the theory of linked ordering schemes1 for ro-vibrational interactions. Non-diagonal matrix elements corresponds the long range electrostatic interactions in the system H2O-H2. Earlier the diagonal matrix elements of intermolecular potential operator were obtained. It is calculated the influence of the vibrational anharmonism on the non-diagonal matrix elements of intermolecular potential does not exceed 12%.

Paper Details

Date Published: 12 January 2004
PDF: 5 pages
Proc. SPIE 5311, 14th Symposium on High-Resolution Molecular Spectroscopy, (12 January 2004); doi: 10.1117/12.545679
Show Author Affiliations
Valentina N. Stroinova, Tomsk Polytechnical Univ. (Russia)
Yurii I. Tyurin, Tomsk Polytechnical Univ. (Russia)
Alexander D. Bykov, Institute of Atmospheric Optics (Russia)
Vladimir M. Mikhailov, Institute of Atmospheric Optics (Russia)


Published in SPIE Proceedings Vol. 5311:
14th Symposium on High-Resolution Molecular Spectroscopy
Leonid N. Sinitsa; Semen N. Mikhailenko, Editor(s)

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