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Proceedings Paper

Steric effects in the chemiluminescent reactions of metastable Ca*(3P) atoms with isomeric alkyl halides
Author(s): B. Pranszke
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Paper Abstract

In the previous paper steric effects in the chemiluminescence reactions of metastable calcium atoms with isomeric propyl halide have been studied. Substantial differences in the CaCl(B2Σ)/CaCl(A2Π) branching ratio were found with isomeric variation of the targets. This has been a motivation for research presented in this work. Reactions of metastable calcium atoms in the metastable 3PJ states with all commercially available normal and branched alkyl halides were studied in a beam-gas arrangement. Chemiluminescence spectra of alkaline earth monohalides were observed for calcium reactions. Total collision and chemiluminescence cross sections were measured.

Paper Details

Date Published: 17 November 2003
PDF: 5 pages
Proc. SPIE 5258, IV Workshop on Atomic and Molecular Physics, (17 November 2003); doi: 10.1117/12.544435
Show Author Affiliations
B. Pranszke, Univ. of Gdansk (Poland)


Published in SPIE Proceedings Vol. 5258:
IV Workshop on Atomic and Molecular Physics
Jozef Heldt, Editor(s)

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