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Proceedings Paper

Novel methylene-blue-sensitized photopolymers for holographic recording: a comparison
Author(s): Mythili Ushamani; K. Sreekumar; C. Sudha Kartha; Rani Joseph
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Paper Abstract

Polymer matrices like PVC and a blend of PVA/PAA is introduced as new holographic media that cause red sensitivity with methylene blue. Unlike methylene blue sensitized polymers like PVA, PMMA, gelatin etc, the change of state occurring for methylene blue on laser irradiation on PVC matrix was found to be permanent. No recovery of dye on the irradiated spot was observed on storage. The outstanding properties of this material are its excellent optical clarity, insensitive to humidity, economical, ease of fabrication, absence of dark room storage etc. The recovery of dye in conventional MBPVA matrix can be delayed by blending PVA with PAA. Optimization of the ratio of PVA/PAA, the sensitizer concentration, pH, energy, diffraction efficiency measurements etc are done. pH is found to have a great influence on the recovery of the dye in this matrix. The effect of monomers in improving the diffraction efficiency on these dye doped polymer system is also evaluated. A comparative study is done on these polymer matrices and holographic gratings were recorded on these films from a He- Ne laser operating at 632.8 nm.

Paper Details

Date Published: 29 June 2004
PDF: 8 pages
Proc. SPIE 5290, Practical Holography XVIII: Materials and Applications, (29 June 2004); doi: 10.1117/12.537762
Show Author Affiliations
Mythili Ushamani, Cochin Univ. of Science and Technology (India)
K. Sreekumar, Cochin Univ. of Science and Technology (India)
C. Sudha Kartha, Cochin Univ. of Science and Technology (India)
Rani Joseph, Cochin Univ. of Science and Technology (India)

Published in SPIE Proceedings Vol. 5290:
Practical Holography XVIII: Materials and Applications
Tung H. Jeong; Hans I. Bjelkhagen, Editor(s)

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