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Proceedings Paper

Higher order dipole moments for rotational transitions in quasidegenerate vibrational states of methane-type molecules
Author(s): Vladimir M. Mikhailov
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Paper Abstract

Effecitve dipole moment operator including higher order coriolis type electrodipole moments is developed for lower dyad states (v2,v4) of methane. Parameters in effective coriolis type dipole moments are calculated as for isolated v2 and v4 vibrational states as dyad (v2,v4) states. It is shown that coriolis type dipole moments for v1 and v3 states the same equation as for dyad (v1,v3) states. For the parameters in M22(R) operator is obtained the value xxxxxxxxx (theor)=-2,2 10-4D in agreement with experimental date of H. Sasada et al[12]:(Θx,y3z)'=Θx,y3z -3Θx,yz ={(top line)-2,9x10-9D(theor)[10,11] (bottom line) -4,4x10-4D(exp)[12]

Paper Details

Date Published: 27 March 2003
PDF: 13 pages
Proc. SPIE 5026, Ninth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics. Part I: Radiation Propagation in the Atmosphere and Ocean, (27 March 2003); doi: 10.1117/12.497180
Show Author Affiliations
Vladimir M. Mikhailov, Institute of Atmospheric Optics (Russia)


Published in SPIE Proceedings Vol. 5026:
Ninth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics. Part I: Radiation Propagation in the Atmosphere and Ocean
Gennadii G. Matvienko; Vladimir P. Lukin, Editor(s)

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