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Proceedings Paper

Polarizability function of diatomic homonuclear molecules
Author(s): Michail A. Buldakov; Victor N. Cherepanov; Ivan I. Matrosov
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Paper Abstract

The new semiempirical calculation method of the polarizability function for diatomic homonuclear molecules in a range R∈(0,∞ ) has been developed. The method is based on the use of the known polarizability function for small R, the polarizability values and their polarizability derivatives in the equilibrium internucelar distance and the elaborated polarizability function of the interacting oriented atoms under greater R, which comprises the atomic polarizability change under their approach, as well as takes into account their multipole interactions. Account of the multipole interaction of atoms is carried out within the framework of the model of two interacting dielectric spheres. The method is tested by the molecule H2 and applied to the calculation of polarizability functions for the N2 and O2 molecules.

Paper Details

Date Published: 27 March 2003
PDF: 6 pages
Proc. SPIE 5026, Ninth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics. Part I: Radiation Propagation in the Atmosphere and Ocean, (27 March 2003); doi: 10.1117/12.497163
Show Author Affiliations
Michail A. Buldakov, Institute of Optical Monitoring (Russia)
Victor N. Cherepanov, Tomsk State Univ. (Russia)
Ivan I. Matrosov, Institute of Optical Monitoring (Russia)


Published in SPIE Proceedings Vol. 5026:
Ninth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics. Part I: Radiation Propagation in the Atmosphere and Ocean

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