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Proceedings Paper

Preparation of polyperinaphthlenic organic semiconductor nanoparticles by excimer laser ablation and application of a few electronic devices
Author(s): Satoru Nishio; Kazuyuki Tamura; Jun Murata; Hirokuni Matsukawa; Junko Kitahara; Teruhiko Kan; Akiyoshi Matsuzaki; Nobuo Ando; Yukinori Hato
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Paper Abstract

Polyperinaphthalenic organic semiconductor (PPNOS) nano-particles are prepared by excimer laser ablation (ELA) of a 3, 4, 9, 10-perylenettracarboxylic dianhydride (PTCDA) target using XeCl excimer laser beams. Heterojunctions of the films consisting of nano-particles of PPNOS with Si wafers are fabricated. Well rectifier property is obtained for the junction of the PPN with a n-Si substrate. Current versus voltage curves of the heterojunction in the dark and under illumination show that the junction is promising as a photovoltaic cell. Furthermore, the films are applied to anode electrodes for ultra thin rechargeable Li ion batteries. In-situ Raman spectroscopy of the films under lithium ion doping and undoping is performed to elucidate the storage mechanism of lithium ion at cis-polyacetylene-type (phenanthrene-edge) of PPN structure.

Paper Details

Date Published: 19 February 2003
PDF: 6 pages
Proc. SPIE 4830, Third International Symposium on Laser Precision Microfabrication, (19 February 2003); doi: 10.1117/12.486574
Show Author Affiliations
Satoru Nishio, Tohoku Univ. (Japan)
Kazuyuki Tamura, Mi'e Univ. (Japan)
Jun Murata, Mi'e Univ. (Japan)
Hirokuni Matsukawa, Mi'e Univ. (Japan)
Junko Kitahara, Mi'e Univ. (Japan)
Teruhiko Kan, Mi'e Univ. (Japan)
Akiyoshi Matsuzaki, Mi'e Univ. (Japan)
Nobuo Ando, Kanebo Ltd. (Japan)
Yukinori Hato, Kanebo Ltd. (Japan)

Published in SPIE Proceedings Vol. 4830:
Third International Symposium on Laser Precision Microfabrication
Isamu Miyamoto; Kojiro F. Kobayashi; Koji Sugioka; Reinhart Poprawe; Henry Helvajian, Editor(s)

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