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Proceedings Paper

New materials for nonlinear optics
Author(s): William E. Douglas; Larisa G. Klapshina; Vladimir Viktotovich Semenov; George A. Domrachev; Zhanna Y. Fominikh; Oleg Leonidovich Antipov; Andrey V. Afanas'ev; Alexander Sergeevich Kuzhelev; Andrey Petrovich Zinoviev; Anatoly Nikolaevich Rubinov; Boris A. Bushuk; Sergey B. Bushuk; Richard G. Jones; Robert E. Benfield; Alkay Mustafa
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Paper Abstract

A variety of novel materials has been synthesized including poly(ethynediyl-arylene-ethynediyl-silylene)s (PEAES) containing hypercoordinate silicon, and films of metal- containing polyacrylonitrile materials. The (chi) (3) properties in various matrices have been investigated by various techniques such as DFWM and Z-scan. The (chi) (3) values are outstandingly high; e.g. sol-gel films incorporating 5-14 mass percent PEAES show Re(chi) (3) equals 3-9 X 10-11 esu, and films of Cr-containing polyacrylonitrile materials synthesized by the polycyanoethylation reaction between acrylonitrile and Ar2Cr show (chi) (3) equals -2.5 X 10-10 esu.

Paper Details

Date Published: 24 July 2002
PDF: 8 pages
Proc. SPIE 4751, ICONO 2001: Nonlinear Optical Phenomena and Nonlinear Dynamics of Optical Systems, (24 July 2002); doi: 10.1117/12.475912
Show Author Affiliations
William E. Douglas, Univ. Montpellier II (France)
Larisa G. Klapshina, G.A. Razuvaev Institute of Organometallic Chemistry (Russia)
Vladimir Viktotovich Semenov, G.A. Razuvaev Institute of Organometallic Chemistry (Russia)
George A. Domrachev, G.A. Razuvaev Institute of Organometallic Chemistry (Russia)
Zhanna Y. Fominikh, G.A. Razuvaev Institute of Organometallic Chemistry (Russia)
Oleg Leonidovich Antipov, Institute of Applied Physics (Russia)
Andrey V. Afanas'ev, Institute of Applied Physics (Russia)
Alexander Sergeevich Kuzhelev, Institute of Applied Physics (Russia)
Andrey Petrovich Zinoviev, Institute of Applied Physics (Russia)
Anatoly Nikolaevich Rubinov, B.I. Stepanov Institute of Physics (Belarus)
Boris A. Bushuk, B.I. Stepanov Institute of Physics (Belarus)
Sergey B. Bushuk, B.I. Stepanov Institute of Physics (Belarus)
Richard G. Jones, Univ. of Kent at Canterbuty (United Kingdom)
Robert E. Benfield, Univ. of Kent (United Kingdom)
Alkay Mustafa, Univ. of Kent (United Kingdom)


Published in SPIE Proceedings Vol. 4751:
ICONO 2001: Nonlinear Optical Phenomena and Nonlinear Dynamics of Optical Systems

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