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Proceedings Paper

Next-generation electroceramic fibers for active control
Author(s): Pavel Bystricky; Marina R. Pascucci; Harold B. Strock
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Paper Abstract

Lead-based PMN-31PT and lead-free BNBZT fibers in the 250- 500 micrometer diameter range were produced using CeraNova's proprietary extrusion technology. Various recrystallization approaches were investigated, including seeded solid state conversion and self-seeded texturing, with the goal of obtaining single-crystalline or textured macrocrystalline fibers. Grains in excess of 100 micrometers - and exceeding 1 mm in some cases - with surface and bulk coverage approaching 100 percent, were obtained in a narrow temperature range and under carefully controlled atmosphere conditions. Large grain growth in BNBZT required the presence of BaSrTiO3 or SrTiO3 seeds and temperatures in the 1150-1200 degrees C range. In PMN-31PT, nearly compete recrystalline was observed in unseeded material at relatively low temperature and short time, and improved performance was achieved with a two-step sintering schedule and slightly extended time. While conduction effects have not yet allowed compete assessment of recrystalline BNBZT, PMN-31PT fibers have shown excellent piezoelectric properties with remanent polarization in excess of 30(mu) C/cm2 and coercive field of 4.5kV/cm. When incorporated into active fiber composites, the latter fibers' performance of 2000 microstrain in superior to average PZT-based production composites. Efforts are under way to induce preferred orientation in the large crystal in order to maximize performance.

Paper Details

Date Published: 11 July 2002
PDF: 9 pages
Proc. SPIE 4699, Smart Structures and Materials 2002: Active Materials: Behavior and Mechanics, (11 July 2002); doi: 10.1117/12.474971
Show Author Affiliations
Pavel Bystricky, CeraNova Corp. (United States)
Marina R. Pascucci, CeraNova Corp. (United States)
Harold B. Strock, CeraNova Corp. (United States)

Published in SPIE Proceedings Vol. 4699:
Smart Structures and Materials 2002: Active Materials: Behavior and Mechanics
Christopher S. Lynch, Editor(s)

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