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Proceedings Paper

High-speed nonsilver lithographic system for laser direct imaging
Author(s): Thap DoMinh
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Paper Abstract

A high-speed nonsilver lithographic system has been demonstrated for direct laser imaging. The system is negative working and is based on a photoinsolubilization of a polymer coating by redox amplification. The essential components consist of a cobalt(III)amine (Coen), a redox transfer ligand (PAN), a light-sensitive quinone (Q), and a polysulfonamide binder (A6). On exposure, the quinone photogenerates a hydroquinone reducing agent. On heating, the hydroquinone reduces Coen to produce Co(II). PAN then complexes this Co(II) to form CO(II) PAN which, in turn, reduces more Coen. This resulting reaction produces Co(III)PAN and more Co(II) centers, which in the presence of excess PAN and Coen continues the cycle, giving photographically useful amplification. Polysulfonamide (A6) is an excellent medium with optimal acidity and thermomechanical properties to promote this chemistry. It provides toughness required for a dry-film photoresist, ink receptivity for lithographic plate, and aqueous development for both applications. Exposure to an Argon ion laser (4881514nm) at dose O.5-lmj/cm2 followed by heating (5 sec/120 C hot plate) produced high-density images that were insolubilized in an aqueous alkaline developer to give final nonswell images of excellent quality.

Paper Details

Date Published: 1 August 1991
PDF: 1 pages
Proc. SPIE 1458, Printing Technologies for Images, Gray Scale, and Color, (1 August 1991); doi: 10.1117/12.46334
Show Author Affiliations
Thap DoMinh, Eastman Kodak Co. (United States)


Published in SPIE Proceedings Vol. 1458:
Printing Technologies for Images, Gray Scale, and Color
Derek B. Dove; Takao Abe; Joachim L. Heinzl, Editor(s)

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