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Proceedings Paper

Photo-induced charge separation in TiO2/porphyrin bilayers studied by time-resolved microwave conductivity
Author(s): Jessica E. Kroeze; Tom J. Savenije; John M. Warman
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Paper Abstract

The electrodeless flash-photolysis time-resolved microwave conductivity technique (FP-TRMC) has been used to study photo-induced interfacial charge separation in bilayers consisting of a smooth, 80 nm layer of anatase TiO2 onto which is spin-coated a 60 nm layer of a tetraphenyl porphyrin derivative with either unsubstituted or para-carboxy-substituted phenyl moieties; "TPP" or "TPPC". No significant difference in sensitization efficiency was observed between TPP and TPPC; both gave a maximum charge separation efficiency per incident photon of ca 1% on irradiation in their Soret band (430 nm). The low efficiency indicates that interfacial charge transfer occurs mainly for excited states produced in the first adsorbed monolayer of the sensitizer. Contrary to previous suggestions, specific interactions between the carboxy groups of TPPC and the TiO2 surface do not appear to favor more efficient charge separation.

Paper Details

Date Published: 26 February 2003
PDF: 13 pages
Proc. SPIE 4801, Organic Photovoltaics III, (26 February 2003); doi: 10.1117/12.452424
Show Author Affiliations
Jessica E. Kroeze, Delft Univ. of Technology (Netherlands)
Tom J. Savenije, Delft Univ. of Technology (Netherlands)
John M. Warman, Delft Univ. of Technology (Netherlands)

Published in SPIE Proceedings Vol. 4801:
Organic Photovoltaics III
Zakya H. Kafafi, Editor(s)

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