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Proceedings Paper

Soluble polyacetylenes derived from the ring-opening metathesis polymerization of substituted cyclooctatetraenes: electrochemical characterization and Schottky barrier devices
Author(s): Thomas H. Jozefiak; Michael J. Sailor; Eric J. Ginsburg; Christopher B. Gorman; Nathan Saul Lewis; Robert H. Grubbs
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Paper Abstract

Recent developments in ring-opening metathesis polymerization (ROMP) have enabled the synthesis of poly-cyclooctatetraene (poly-COT), a material which is isostructural to polyacetylene. This liquid-phase polymerization method allows facile construction of interfaces, films, and devices with polyacetylene-like materials. The ROMP method also allows the preparation of soluble, yet highly conjugated polyacetylene analogs from substituted cyclooctatetraenes (R-COT). The redox characteristics of R-COT polymers were investigated at electrodes modified with thin polymer films. Voltammetric methods were used to characterize the redox response, band gap, electrochemical doping, and cis-trans isomerization properties of these polyenes. We have applied poly-COT technology to the fabrication of Schottky diodes and photoelectrochemical cells, by forming poly-COT films on semiconductor surfaces. The resultant semiconductor/organic-metal interfaces behave more ideally than semiconductor contacts with conventional metals, in that changes in the work function of the conducting polymer exert a large and predictable effect on the electrical properties of the resulting Schottky diodes. Transparent films of the solution-processible polymer poly- trimethylsilyl-cyclooctatetraene (poly-TMS-COT) have been cast onto n-silicon substrates and doped with iodine to form surface barrier solar cells. These devices produce photovoltages that are much larger than can be obtained from n-silicon contacts with conventional metals.

Paper Details

Date Published: 1 March 1991
PDF: 12 pages
Proc. SPIE 1436, Photochemistry and Photoelectrochemistry of Organic and Inorganic Molecular Thin Films, (1 March 1991); doi: 10.1117/12.45109
Show Author Affiliations
Thomas H. Jozefiak, California Institute of Technology (United States)
Michael J. Sailor, California Institute of Technology (United States)
Eric J. Ginsburg, California Institute of Technology (United States)
Christopher B. Gorman, California Institute of Technology (United States)
Nathan Saul Lewis, California Institute of Technology (United States)
Robert H. Grubbs, California Institute of Technology (United States)


Published in SPIE Proceedings Vol. 1436:
Photochemistry and Photoelectrochemistry of Organic and Inorganic Molecular Thin Films
Marcus F. Lawrence; Arthur Jesse Frank; S. Ramasesha; Carl C. Wamser, Editor(s)

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