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Proceedings Paper

Electrochemically driven actuators from conducting polymers, hydrogels, and carbon nanotubes
Author(s): Geoffrey M. Spinks; Gordon G. Wallace; Trevor W. Lewis; Leonard S. Fifield; Liming Dai; Ray H. Baughman
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Paper Abstract

The mechanisms of actuation operating in polymeric actuators are reviewed along with a comparison of actuator performance. Polymer hydrogel actuators show very large dimensional changes, but relatively low response times. The mechanism of actuation involves several processes including electro-osmosis and electrochemical effects. Conducting polymer actuators operate by Faradaic reactions causing oxidation and reduction of the polymer backbone. Associated ion movements produce dimensional changes of typically up to 3%. The maximum stress achieved to date from conducting polymers is not more than 10 MPA. Carbon nanotubes have recently been demonstrated as new actuator materials. The nanotubes undergo useful dimensional changes (approximately 1%) but have the capacity to respond very rapidly (kHz) and generate giant stresses (600 MPa). The advantages of nanotube actuators stem from their exceptional mechanical properties and the non-Faradaic actuation mechanism.

Paper Details

Date Published: 6 April 2001
PDF: 9 pages
Proc. SPIE 4234, Smart Materials, (6 April 2001); doi: 10.1117/12.424410
Show Author Affiliations
Geoffrey M. Spinks, Univ. of Wollongong (Australia)
Gordon G. Wallace, Univ. of Wollongong (Australia)
Trevor W. Lewis, Univ. of Wollongong (Australia)
Leonard S. Fifield, Univ. of Washington (United States)
Liming Dai, CSIRO (United States)
Ray H. Baughman, Honeywell International (United States)

Published in SPIE Proceedings Vol. 4234:
Smart Materials
Alan R. Wilson; Hiroshi Asanuma, Editor(s)

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