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Proceedings Paper

Vibrational dependence of mean polarizability of quasi-rigid molecules
Author(s): Vladimir M. Mikhailov; Valentina N. Stroinova
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Paper Abstract

In the paper the conception of Pade-approximants in the framework of broadening theory of spectral lines was presented as an example of the generation of effective polarizability operators in excited vibrational states of three atomic quasi- rigid molecules. This conception is a part of the theory of linked ordering schemes of intra- and intermolecular interactions in polyatomic molecules. In the framework of the theory of linked ordering schemes in the limited ordering scheme corresponding to super excited oscillator model the vibrational dependence of mean polarizability for H2O molecule in the form of Taylor series on the power of vibrational quantum numbers is proved. Taylor series was summed up using Pade-approximants technique.

Paper Details

Date Published: 29 December 2000
PDF: 6 pages
Proc. SPIE 4341, Seventh International Symposium on Atmospheric and Ocean Optics, (29 December 2000); doi: 10.1117/12.412000
Show Author Affiliations
Vladimir M. Mikhailov, Institute of Atmospheric Optics (Russia)
Valentina N. Stroinova, Tomsk Polytechnical Univ. (Russia)

Published in SPIE Proceedings Vol. 4341:
Seventh International Symposium on Atmospheric and Ocean Optics
Gennadii G. Matvienko; Mikhail V. Panchenko, Editor(s)

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