Share Email Print
cover

Proceedings Paper

Temperature dependence of the C1+HN3 reaction from 300 to 480 K
Author(s): Gerald C. Manke II; Thomas L. Henshaw; Timothy J. Madden; Gordon D. Hager
Format Member Price Non-Member Price
PDF $17.00 $21.00

Paper Abstract

The rate constant for Cl + HN3 over the temperature range 300-480 K has been studied in a flow reactor. Based on the rate of loss of HN3 and the rate of NCL(a1(Delta) ) generation, the temperature dependence of this reaction is described by the collision theory expression 1.2 +/- 0.3 X 10-11 T0.5 exp(-1514 +/- 93/T), with E0 equals 3.0 +/- 0.2 kcal mol-1 or an Arrhenius fit k(T) equals 2.0 +/- 1.0 X 10-10 exp(-1452 +/- 150/T) with Ea equals 2.9 +/- 0.2 kcal mol-1.

Paper Details

Date Published: 4 May 2000
PDF: 11 pages
Proc. SPIE 3931, Gas, Chemical, and Electrical Lasers and Intense Beam Control and Applications, (4 May 2000); doi: 10.1117/12.384267
Show Author Affiliations
Gerald C. Manke II, Air Force Research Lab. (United States)
Thomas L. Henshaw, Air Force Research Lab. (United States)
Timothy J. Madden, Air Force Research Lab. (United States)
Gordon D. Hager, Air Force Research Lab. (United States)


Published in SPIE Proceedings Vol. 3931:
Gas, Chemical, and Electrical Lasers and Intense Beam Control and Applications
Santanu Basu; Santanu Basu; Steven J. Davis; Ernest A. Dorko, Editor(s)

© SPIE. Terms of Use
Back to Top