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Proceedings Paper

Effective quadrupole coupling operator for quasi-degenerate vibrational states of polyatomic molecules in the theory of linked ordering schemes of rovibrational interactions
Author(s): Vladimir M. Mikhailov
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Paper Abstract

The contribution have been devoted the construction of effective quadrupole coupling operator for quasidegenerate vibrational levels of polyatomic molecules and the reduction of the laser. The indeterminacy problem of the parameters in the effective vibrational-rotational HeffVR and quadrupole Weff Hamiltonians for the cases of accidental resonances linked with various groupings of vibrational- rotational interactions (problem of grouping uncertainty) are considered. The problem of the reduction of Heff equals HeffVR + Weff is discussed. The case of the Coriolis-type, accidental resonances have been considered more detail. New representation of Heff equals HeffVR + Weff for isolated vibration levels in form of angular moments only is presented.

Paper Details

Date Published: 25 January 2000
PDF: 8 pages
Proc. SPIE 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy, (25 January 2000); doi: 10.1117/12.375366
Show Author Affiliations
Vladimir M. Mikhailov, Institute of Atmospheric Optics (Russia)


Published in SPIE Proceedings Vol. 4063:
13th Symposium and School on High-Resolution Molecular Spectroscopy

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