Share Email Print
cover

Proceedings Paper

Second-order nonlinear optical films for alternating polyelectrolyte deposition
Author(s): Geoffrey A. Lindsay; M. Joseph Roberts; John D. Stenger-Smith; Peter Zarras; Richard A. Hollins; Andrew P. Chafin; Rena Y. Yee; Kenneth J. Wynne
Format Member Price Non-Member Price
PDF $14.40 $18.00

Paper Abstract

This is a preliminary report on alternating polyelectrolyte deposition (APD) with the goal of making electro-optic films at room temperature. By means of the APD method, films were built up layer-by-layer at room temperature by a dipping process. APD requires two complementary polymers, one being negatively charged and the other being positively charged. The polymer in solution is attracted to the solid substrate by coulombic forces to form the next layer on the substrate. For the first time, second-order nonlinear optical (NLO) polymer films were prepared by APD in which both polymers were NLO-active. The cationic polymer contained a side-chain stilbazole chromophore, and the anionic polymer contained a main-chain cinnamoyl chromophore. The intensity of the second harmonic signal generated in the film increased quadratically with each layer for the first twenty layers.

Paper Details

Date Published: 29 October 1998
PDF: 5 pages
Proc. SPIE 3474, Second-Order Organic Nonlinear Optics, (29 October 1998); doi: 10.1117/12.328582
Show Author Affiliations
Geoffrey A. Lindsay, Naval Air Warfare Ctr. (United States)
M. Joseph Roberts, Naval Air Warfare Ctr. (United States)
John D. Stenger-Smith, Naval Air Warfare Ctr. (United States)
Peter Zarras, Naval Air Warfare Ctr. (United States)
Richard A. Hollins, Naval Air Warfare Ctr. (United States)
Andrew P. Chafin, Naval Air Warfare Ctr. (United States)
Rena Y. Yee, Naval Air Warfare Ctr. (United States)
Kenneth J. Wynne, Office of Naval Research (United States)


Published in SPIE Proceedings Vol. 3474:
Second-Order Organic Nonlinear Optics
Manfred Eich, Editor(s)

© SPIE. Terms of Use
Back to Top