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Proceedings Paper

Laser machining of specially designed photopolymers: photochemical ablation mechanism
Author(s): Thomas K. Lippert; J. Thomas Dickinson; Steve C. Langford; H. Furutani; H. Fukumura; Hiroshi M. Masuhara; Thilo Kunz; Alexander J. Wokaun
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Paper Abstract

Photopolymers based on the triazeno chromophore group (-NequalsN-N<) have been developed. The absorption properties can be tailored for a specific irradiation wavelength (e.g. 308 cm XeCl laser). The photochemical exothermic decomposition yields high energetic gaseous products which are not contaminating the surface. The polymer can be structured with high resolution. No debris has been found around the etched corners. Maximum ablation rates of about 3 micrometers / pulse were achieved due to the dynamic absorption behavior (bleaching during the pulse). No physical or chemical modifications of the polymer surface could be detected after irradiation at the tailored absorption wavelength, whereas irradiation at different wavelengths resulted in modified (physical and chemical) surfaces. The etching of the polymer starts and ends with the laser pulse, shown by ns-interferometry, confirming that the acting mechanism is mainly photochemical. TOF-MS revealed fragments which are also totally compatible with a photochemical decomposition mechanism.

Paper Details

Date Published: 26 May 1998
PDF: 8 pages
Proc. SPIE 3404, ALT'97 International Conference on Laser Surface Processing, (26 May 1998); doi: 10.1117/12.308615
Show Author Affiliations
Thomas K. Lippert, Los Alamos National Lab. (United States)
J. Thomas Dickinson, Washington State Univ. (United States)
Steve C. Langford, Washington State Univ. (United States)
H. Furutani, Osaka Univ. (Japan)
H. Fukumura, Osaka Univ. (Japan)
Hiroshi M. Masuhara, Osaka Univ. (Japan)
Thilo Kunz, Paul Scherrer Institute (Switzerland)
Alexander J. Wokaun, Paul Scherrer Institute (Switzerland)


Published in SPIE Proceedings Vol. 3404:
ALT'97 International Conference on Laser Surface Processing
Vladimir I. Pustovoy, Editor(s)

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