Share Email Print
cover

Proceedings Paper

Spectroscopy and dynamics involving interacting electronic states
Author(s): Hans-Peter Loock; Jianying Cao; Walter J. Balfour; Chi Zhou; Charles Qian
Format Member Price Non-Member Price
PDF $14.40 $18.00
cover GOOD NEWS! Your organization subscribes to the SPIE Digital Library. You may be able to download this paper for free. Check Access

Paper Abstract

The deperturbation analysis of ReN and nonadiabatic dissociation dynamics of BrCl and BrNO are reported. In the case of ReN, couplings between different electronic states changes apparent molecular properties such as rotational constants and excited state lifetimes. An experimental approach which enabled us to separated the contributions to the mixed states from specified energies and the spin-orbit branching ratio was measured as a function of the excitation energy. The correlation of the spin-orbit states of the photofragments was established. Such observations enabled us to establish nonadiabatic dissociation mechanisms. In both the spectroscopy and dissociation dynamics studies, the coupling between the nuclear and electronic degrees of freedom was investigated.

Paper Details

Date Published: 15 May 1998
PDF: 4 pages
Proc. SPIE 3271, Laser Techniques for State-Selected and State-to-State Chemistry IV, (15 May 1998); doi: 10.1117/12.308386
Show Author Affiliations
Hans-Peter Loock, Univ. of Victoria (Canada)
Jianying Cao, Univ. of Victoria (Canada)
Walter J. Balfour, Univ. of Victoria (Canada)
Chi Zhou, Univ. of Victoria (United States)
Charles Qian, Univ. of Victoria (United States)


Published in SPIE Proceedings Vol. 3271:
Laser Techniques for State-Selected and State-to-State Chemistry IV
John W. Hepburn; Robert E. Continetti; Mark A. Johnson, Editor(s)

© SPIE. Terms of Use
Back to Top