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Proceedings Paper

Characterization and optimization of positive-tone DUV resists on TiN substrates
Author(s): Peter Zandbergen; Wendy F.J. Gehoel-van Ansem; Geert Vandenberghe; Veerle Van Driessche; Hans Vloeberghs
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Paper Abstract

Chemically amplified resists are notoriously sensitive to substrate contaminations. Such substrates include Si3N4, SOG, SiO2 and TiN. Contaminations can result in deactivation of the acid catalyst, leading to resist footing for positive tone deep UV resists. In this paper we have tested several state of the art deep UV resists on TiN. Through cross-sectional inspections, it was seen that several of the most advanced resists available still suffer from footing on TiN. By varying the process parameters of the TiN PVD process, TiN layers with various ratios of Ti:N were obtained. Variations in TiN composition result in changes of deactivation of acid catalyst. In addition, optical properties of the TiN layer are changed as well, resulting in different resist performances. For resists suffering from footing on TiN, it was demonstrated that footing is related to the nitrogen saturation of the TiN layer. However, for ARCH2 resist series, no resist footing was seen on different TiN layers. For the optimization of deep UV patterning of 0.25 micrometers CMOS metal layers using standard TiN layers, we have tested several resists of the ARCH2 resist series. The series of resists are based on the same resist chemistry. The difference between the formulations is in their absorbance, being 0.21/micrometer, 0.28/micrometer and 0.44/micrometer for ARCH214, ARCH212, and ARCH200, respectively. It was seen that with transparent resists notching can occur due to substrate roughnesses. By increasing the resist thickness and/or the resist absorbance, notching was minimized.

Paper Details

Date Published: 7 July 1997
PDF: 10 pages
Proc. SPIE 3049, Advances in Resist Technology and Processing XIV, (7 July 1997); doi: 10.1117/12.275832
Show Author Affiliations
Peter Zandbergen, Philips Research Labs. (Netherlands)
Wendy F.J. Gehoel-van Ansem, Philips Research Labs. (Netherlands)
Geert Vandenberghe, IMEC (Belgium)
Veerle Van Driessche, Olin Microelectronic Materials (Belgium)
Hans Vloeberghs, Olin Microelectronic Materials (Belgium)


Published in SPIE Proceedings Vol. 3049:
Advances in Resist Technology and Processing XIV
Regine G. Tarascon-Auriol, Editor(s)

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