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On the role of different paramagnetic centers in conducting nickel oxide thin films
Author(s): Angela Ebere Ezugwu; Victor Wong; Paul Bazylewski; Giovanni Fanchini
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Paper Abstract

Transparent conducting oxides (TCOs) are extensively investigated because of their applications as transparent electrodes in solar cells and light-emitting devices. TCOs of interest include indium-tin oxide, aluminum-doped zinc oxide, nickel oxide (NiO), and their combinations. There is strong interest in NiO because no heteroatoms are required to “dope” it at high transparency levels. It has been speculated that paramagnetic defects due to Ni3+ centers and O interstitials are responsible for the electrical conductivity of otherwise insulating and antiferromagnetic NiO, but direct investigation of such defects has been limited. Here, the electrical conductivity in nanostructured NiO thin films is investigated and correlated to the paramagnetic defect density extracted from electron spin resonance (ESR). Two types of ESR-active centers are identified. Our work points at defect engineering as a necessary step to optimize NiO thin films for their applications as TCOs.

Paper Details

Date Published: 1 March 2019
PDF: 12 pages
Proc. SPIE 10919, Oxide-based Materials and Devices X, 109191G (1 March 2019); doi: 10.1117/12.2509171
Show Author Affiliations
Angela Ebere Ezugwu, Western Univ. (Canada)
Victor Wong, Western Univ. (Canada)
Paul Bazylewski, Western Univ. (Canada)
Giovanni Fanchini, Western Univ. (Canada)

Published in SPIE Proceedings Vol. 10919:
Oxide-based Materials and Devices X
David J. Rogers; David C. Look; Ferechteh H. Teherani, Editor(s)

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