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Proceedings Paper

Defect control in crystal growth of photorefractive materials
Author(s): Kenji Kitamura; Nobuo Iyi; Junzo Tanaka
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Paper Abstract

Some multi-component photorefractive crystals exhibit wide variations in their properties associated with the nonstoichiometry of the constituent cations. In order to grow single crystals with high quality and high homogeneity under nonstoichiometry control, a double crucible Czochralski method has been developed. In this method, the melt was divided into two parts by a double structure (two chamber system) crucible. The crystal was grown from the inner melt, and a powder with the same composition as the growing crystal was supplied to the outer melt. The powder was supplied continuously and smoothly at the rate of weight increase of the growing crystal. This rate was automatically controlled to match the weight increase of the growing crystals as monitored by a load cell. As an example, LiNbO3 single crystals with a composition close to stoichiometric were grown, and their photorefractive properties were compared with those of Nb-rich congruent LiNbO3 crystal. As the result, it turned out that the stoichiometric LN crystal exhibited higher efficiency and faster responsivity than the congruent crystal.

Paper Details

Date Published: 26 April 1996
PDF: 5 pages
Proc. SPIE 2779, 3rd International Conference on Intelligent Materials and 3rd European Conference on Smart Structures and Materials, (26 April 1996); doi: 10.1117/12.237062
Show Author Affiliations
Kenji Kitamura, National Institute for Research in Inorganic Materials (Japan)
Nobuo Iyi, National Institute for Research in Inorganic Materials (Japan)
Junzo Tanaka, National Institute for Research in Inorganic Materials (Japan)


Published in SPIE Proceedings Vol. 2779:
3rd International Conference on Intelligent Materials and 3rd European Conference on Smart Structures and Materials

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