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Proceedings Paper

Prospects for broadband spectrum Raman optical refrigeration
Author(s): Rachel Tyo; Claire Alvine; Zacarias Imperial; Kimberly Rosal; Reid Vorbach; Mostafa Sadoqi; C. M. Fortmann
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Paper Abstract

Described are the prospects for broadband optical refrigeration based on Raman scattering of incoherent light. Laser pumped rare earth fluorescence has been demonstrated and commercial applications are sure to follow. Broadband refrigeration requires strong Raman scattering and large Raman shift. Also required are spectral management and photonic patterning to offset the unfavorable anti-Stoke’s to Stoke’s shift ratio. Materials such as diamond, silicon, and a number of molecular systems are ideal and have low absorption. Optics splits the broadband spectrum into light and dark bands with width corresponding to the Raman shift. Broadband spectrums where photon flux decreases with increasing photon energy are ideal. By tailoring the incoming spectrum, by utilizing extremely transparent strong Raman shift materials and by photonic inhibition of Stoke’s shifted light the prospect become feasible. The Raman optical cross- section increases with decreasing particle size (until the particle become too small to support the Raman-phonons). Where conservation of phonon states in these truncated Brillioun-zone particles requires an increased density (number/cm3) of the allowed-states to compensate for states lost to particle size. Nonetheless, the anti-Stokes to Stokes ratio is approximately one-to-two at laboratory temperature. Thin film deposited diamond is an excellent candidate for refrigeration applications due to its high transparency small grain size and its large Raman magnitude and large shift. Simple one-dimensional photonic structures selectively inhibit the Stoke’s shifted light making refrigeration possible.

Paper Details

Date Published: 14 September 2018
PDF: 8 pages
Proc. SPIE 10758, Nonimaging Optics: Efficient Design for Illumination and Solar Concentration XV, 107580J (14 September 2018); doi: 10.1117/12.2322570
Show Author Affiliations
Rachel Tyo, St. John's Univ. (United States)
Claire Alvine, St. John's Univ. (United States)
Zacarias Imperial, St. John's Univ. (United States)
Kimberly Rosal, St. John's Univ. (United States)
Reid Vorbach, St. John's Univ. (United States)
Mostafa Sadoqi, St. John's Univ. (United States)
C. M. Fortmann, St. John's Univ. (United States)

Published in SPIE Proceedings Vol. 10758:
Nonimaging Optics: Efficient Design for Illumination and Solar Concentration XV
Roland Winston; Eli Yablonovitch, Editor(s)

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