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Proceedings Paper

Photonics of boron fluoride and zinc dipyrromethene complexes
Author(s): Iuliia V. Aksenova; Alexander A. Prokopenko; Rimma T. Kuznetsova; Georgy V. Mayer; Natalia A. Bumagina; Mikhail B. Berezin
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Paper Abstract

Spectral, photophysical, photochemical characteristics for mononuclear and binuclear dipyrromethenes in complexes with BF2 (BODIPY), bis-BODIPY and bis-helicates ([Zn2(L)2]) are described. The role of substituents (type and location in the ligand) and the medium in which dipyrromethene complexes are placed (solvents, solid-state matrices), the effect of different complexing agents (p- and d-elements) on the photonics of the complexes are discussed. The results of studying the lasing and photochemical properties of complexes under the action of laser irradiation are presented. In addition, for the described complexes the stability in the ground and excited states in protic media are estimated. Based on the analysis of the results discussed possibilities of practical application of these compounds to creating various optical devices.

Paper Details

Date Published: 16 April 2018
PDF: 7 pages
Proc. SPIE 10614, International Conference on Atomic and Molecular Pulsed Lasers XIII, 106142A (16 April 2018); doi: 10.1117/12.2305471
Show Author Affiliations
Iuliia V. Aksenova, National Research Tomsk State Univ. (Russian Federation)
Alexander A. Prokopenko, National Research Tomsk State Univ. (Russian Federation)
Rimma T. Kuznetsova, National Research Tomsk State Univ. (Russian Federation)
Georgy V. Mayer, National Research Tomsk State Univ. (Russian Federation)
Natalia A. Bumagina, Institute of Solution Chemistry (Russian Federation)
Mikhail B. Berezin, Institute of Solution Chemistry (Russian Federation)


Published in SPIE Proceedings Vol. 10614:
International Conference on Atomic and Molecular Pulsed Lasers XIII
Andrei M. Kabanov; Victor F. Tarasenko, Editor(s)

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