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Proceedings Paper

Excited-state dynamics of C60 and n2-C60Pd(PPh3)2
Author(s): Jonathan D. Callaghan; N. T. H. White; Declan N. Weldon; G. S. Beddard; Werner J. Blau
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Paper Abstract

Transient absorption and pump-probe experiments have been performed on degassed toluene solutions of C60 and eta2-C60Pd(PPh3)2. Previous reports of a 1.2 ns singlet state lifetime for C60 have been confirmed. For the eta2-C60Pd(PPh3)2 compound an extremely fast decay of 12 ps has been observed which is believed to be derived from the rapid depopulation of a charge transfer band which has formed due to electron transfer from metal to ligand.

Paper Details

Date Published: 8 December 1995
PDF: 3 pages
Proc. SPIE 2530, Fullerenes and Photonics II, (8 December 1995); doi: 10.1117/12.228114
Show Author Affiliations
Jonathan D. Callaghan, Trinity College (Ireland)
N. T. H. White, Univ. of Manchester (United Kingdom)
Declan N. Weldon, Trinity College (Ireland)
G. S. Beddard, Univ. of Manchester (United Kingdom)
Werner J. Blau, Trinity College (Ireland)

Published in SPIE Proceedings Vol. 2530:
Fullerenes and Photonics II
Zakya H. Kafafi, Editor(s)

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