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Proceedings Paper

Crystal structure and optical properties of a neodymium trifluoroacetate complex for liquid laser
Author(s): Jiangbo She; Rongzhi Nie; Xin Sun; Bo Peng
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Paper Abstract

The neodymium trifluoroacetate complex was synthesized and characterized by single-crystal X-ray diffraction, elemental and TG analysis, FT-IR spectra, and PL spectra. The optical properties of the liquid medium were studied. From the absorption and luminescence spectra, the Judd-Ofelt parameters of the Nd(CF3COO)3 dissovled in phosphorus oxychloride were obtained. Based on the crystal structure, the effects of crystal field and bond valance properties on three intensity parameters Ωt(t=2,4,6) and emission cross-section were analyzed in detail. The emission cross-section of 4F3/24I11/2 fluorescence transition (3.63×10-20cm2) of the new neodymium compound was higher than those of other Nd(III) complexes and even comparable with some laser glasses

Paper Details

Date Published: 28 February 2017
PDF: 6 pages
Proc. SPIE 10256, Second International Conference on Photonics and Optical Engineering, 102564Z (28 February 2017); doi: 10.1117/12.2260699
Show Author Affiliations
Jiangbo She, Xi'an Institute of Optics and Precision Mechanics (China)
Rongzhi Nie, Xi'an Institute of Optics and Precision Mechanics (China)
Xin Sun, Shaanxi Normal Univ. (China)
Bo Peng, Xi'an Institute of Optics and Precision Mechanics (China)


Published in SPIE Proceedings Vol. 10256:
Second International Conference on Photonics and Optical Engineering
Chunmin Zhang; Anand Asundi, Editor(s)

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