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Proceedings Paper

NLO properties of formyl-methoxy derivatives of [2.2] paracyclophane containing the donor group in different positions
Author(s): Lada N. Puntus; Kyrill Yu. Suponitsky; Dmitrii Antonov; Irina S. Pekareva; Konstantin A. Lyssenko; François Kajzar
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Paper Abstract

Formyl-methoxy derivatives of [2.2]paracyclophane (pCp) have been synthesized and studied by optical spectroscopy as well as the X-ray diffraction method. These molecules crystallize in acentric space groups. The efficiency of SHG ability of these compounds was measured by the powder technique at 1064 nm fundamental wavelength and average NLO susceptibility for some of them was found comparable with such well-known NLO crystal as NPP. The calculations of molecular and crystalline nonlinearities within density functional theory using M052X/6-31+G* level of approximation were also conducted for the considered series of compounds.

Paper Details

Date Published: 31 October 2014
PDF: 12 pages
Proc. SPIE 9253, Optics and Photonics for Counterterrorism, Crime Fighting, and Defence X; and Optical Materials and Biomaterials in Security and Defence Systems Technology XI, 92530W (31 October 2014); doi: 10.1117/12.2069657
Show Author Affiliations
Lada N. Puntus, Kotel’nikov Institute of Radio Engineering and Electronics (Russian Federation)
A.N. Nesmeyanov Institute of Organoelement Compounds (Russian Federation)
Kyrill Yu. Suponitsky, A.N. Nesmeyanov Institute of Organoelement Compounds (Russian Federation)
Dmitrii Antonov, A.N. Nesmeyanov Institute of Organoelement Compounds (Russian Federation)
Irina S. Pekareva, Kotel’nikov Institute of Radio Engineering and Electronics (Russian Federation)
Konstantin A. Lyssenko, A.N. Nesmeyanov Institute of Organoelement Compounds (Russian Federation)
François Kajzar, Univ. Politehnica of Bucharest (France)
Institut des Sciences et Technologies Moléculaires d’Angers, CNRS, Angers Univ. (France)


Published in SPIE Proceedings Vol. 9253:
Optics and Photonics for Counterterrorism, Crime Fighting, and Defence X; and Optical Materials and Biomaterials in Security and Defence Systems Technology XI
Roberto Zamboni; François Kajzar; Attila A. Szep; Douglas Burgess; Gari Owen; Harbinder Rana, Editor(s)

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