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Proceedings Paper

Electro-optical parameters in excited states of some spectrally active molecules
Author(s): Andreea Celia Benchea; Valentina Closca; Cristina Marcela Rusu; Cezarina Morosanu; Dana Ortansa Dorohoi
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Paper Abstract

The spectral shifts measured in different solvents are expressed as functions of the solvent macroscopic parameters. The value of the correlation coefficient multiplying the functions of electric permittivity was determined by statistical means. The correlation coefficient depends on the electric dipole moment of the spectrally active molecules. The electro-optical parameters in the ground state of the solute molecules can be approximated by molecular modeling. The excited state parameters are usually estimated using the results obtained both by HyperChem Programme and solvatochromic study. The importance of this approximate method is that it offers information about of the excited state of solute molecule for which our measuring possibilities are very restrictive. The information about the excited electronic state is affected by the limits in which the theories of liquid solutions are developed. Our results refer to two molecules of vitamins from B class, namely B3 and B6.

Paper Details

Date Published: 22 August 2014
PDF: 8 pages
Proc. SPIE 9286, Second International Conference on Applications of Optics and Photonics, 928649 (22 August 2014); doi: 10.1117/12.2063773
Show Author Affiliations
Andreea Celia Benchea, Univ. Alexandru Ioan Cuza (Romania)
Valentina Closca, Univ. Alexandru Ioan Cuza (Romania)
Cristina Marcela Rusu, Univ. Alexandru Ioan Cuza (Romania)
Cezarina Morosanu, Univ. Alexandru Ioan Cuza (Romania)
Dana Ortansa Dorohoi, Univ. Alexandru Ioan Cuza (Romania)


Published in SPIE Proceedings Vol. 9286:
Second International Conference on Applications of Optics and Photonics
Manuel Filipe P. C. Martins Costa; Rogério Nunes Nogueira, Editor(s)

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