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Proceedings Paper

A toy model for the nonlinear optical response of molecules with modulated conjugation
Author(s): Quanhang Chen; Surbhi Hablani; Jie Li; Javier Perez-Moreno
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Paper Abstract

In organic molecules, the optical response originates from the motion of the pi-electrons, which are constrained to move along the molecule’s conjugated path. As an electron moves through the conjugated path, it interacts with the rest of the charges such that its motion is very dependent on the shape of the molecule. In this paper we introduce a simple model for that allows us to determine how the shape of the conjugated path affects the nonlinear optical response of the molecule. Our results apply to typical second-order dipolar structures: we have determined how the symmetry of the conjugated path affects the optical response, and we have found potential new strategies for making better molecules.

Paper Details

Date Published: 27 October 2014
PDF: 8 pages
Proc. SPIE 9181, Light Manipulating Organic Materials and Devices, 918110 (27 October 2014); doi: 10.1117/12.2062471
Show Author Affiliations
Quanhang Chen, Skidmore College (United States)
Surbhi Hablani, Skidmore College (United States)
Jie Li, Skidmore College (United States)
Javier Perez-Moreno, Skidmore College (United States)
Washington State Univ. (United States)


Published in SPIE Proceedings Vol. 9181:
Light Manipulating Organic Materials and Devices
Jean-Michel Nunzi, Editor(s)

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