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Proceedings Paper

Taxonomy, chemical bonding relations and nonlinear optical properties of noncentrosymmetric sulfide crystals
Author(s): Laiming Zhang; Victor Atuchin; Boris Kidyarov; Yury Andreev
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Paper Abstract

A set of ~450 noncentrosymmetric sulfides has been observed in reference to nonlinear optical properties. It has been found that on the plane of the oxide bond lengths the noncentrosymmetric sulfide crystals are dominantly positioned into a rosette of two intersected ellipses of «acentricity». The strongly non-monotonic dependency of nonlinear optical susceptibility χ(2) on the shortest chemical bond length L(E,M-S) has been obtained for sulfides. The suggested crystal chemistry analysis is useful for searching new noncentrosymmetric sulfide crystals.

Paper Details

Date Published: 16 May 2013
PDF: 6 pages
Proc. SPIE 8796, 2nd International Symposium on Laser Interaction with Matter (LIMIS 2012), 87962A (16 May 2013); doi: 10.1117/12.2010566
Show Author Affiliations
Laiming Zhang, Changchun Institute of Optics, Fine Mechanics and Physics (China)
Victor Atuchin, A.V. Rzhanov Institute of Semiconductor Physics (Russian Federation)
Boris Kidyarov, A.V. Rzhanov Institute of Semiconductor Physics (Russian Federation)
Yury Andreev, Institute for Monitoring of Climatic and Ecological Systems (Russian Federation)


Published in SPIE Proceedings Vol. 8796:
2nd International Symposium on Laser Interaction with Matter (LIMIS 2012)
Stefan Kaierle; Jingru Liu; Jianlin Cao, Editor(s)

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