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Proceedings Paper

Photochemistry of the N2O-H2O complexes produced in supersonic jets
Author(s): Ichiro Hanazaki; Hong-Lae Kim; Masao Takayanagi
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Paper Abstract

We have studied 193 nm photodissociation of N2O(DOT)H2O complexes produced in a supersonic jet resulting in the reactant-pair reaction N2O(DOT)H2O + hv yields 2OH + N2. Measured internal energy, and spin-orbit and (Lambda) -doublet distributions in OH by laser induced fluorescence suggest a reaction scheme much different from the corresponding bimolecular reaction, O(1D) + H2O yields 2OH, observed in bulb experiments. The reaction should occur indirectly with early escape of N2 and proceed slowly in a relatively long-lived intermediate O(DOT)H2O.

Paper Details

Date Published: 17 June 1994
PDF: 6 pages
Proc. SPIE 2124, Laser Techniques for State-Selected and State-to-State Chemistry II, (17 June 1994); doi: 10.1117/12.178110
Show Author Affiliations
Ichiro Hanazaki, Institute for Molecular Science (Japan)
Hong-Lae Kim, Kangweon National Univ. (South Korea)
Masao Takayanagi, Institute for Molecular Science (Japan)

Published in SPIE Proceedings Vol. 2124:
Laser Techniques for State-Selected and State-to-State Chemistry II
John W. Hepburn, Editor(s)

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