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Proceedings Paper

Fourier transform infrared and FT-Raman studies on tetranuclear oxo-centered carboxylate complexes of zinc (II)
Author(s): O. Berkesi; I. Dreveni; J. A. Andor; U. A. Jayasooriya; R. D. Cannon; J. Mink
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Paper Abstract

A selection of stable Zn4O(RCOO)6 complexes have been studied by FT-IR and FT- Raman spectroscopy. Polarized FT-Raman studies of two samples, which were in liquid state at ambient temperature, have also been completed. An attempt was made to construct the kinetic energy matrix for a simplified model involving 29 atoms with Td symmetry. A set of symmetry coordinates was chosen to describe the vibrational behavior of the molecule and serve as a base for future force-field calculations. The characteristic frequencies of A1 and T2 species were assigned. Some of the E modes were also obtained.

Paper Details

Date Published: 31 January 1994
PDF: 2 pages
Proc. SPIE 2089, 9th International Conference on Fourier Transform Spectroscopy, (31 January 1994); doi: 10.1117/12.166781
Show Author Affiliations
O. Berkesi, Attila Jozef Univ. (Hungary)
I. Dreveni, Attila Jozef Univ. (Hungary)
J. A. Andor, Attila Jozef Univ. (Hungary)
U. A. Jayasooriya, Univ. of East Anglia (United Kingdom)
R. D. Cannon, Univ. of East Anglia (United Kingdom)
J. Mink, Institute of Isotopes (Hungary)


Published in SPIE Proceedings Vol. 2089:
9th International Conference on Fourier Transform Spectroscopy
John E. Bertie; Hal Wieser, Editor(s)

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