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Proceedings Paper

Matrix isolation infrared spectroscopic studies of some boron trifluoride complexes
Author(s): L. M. Nxumalo; T. A. Ford
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Paper Abstract

The infrared spectra of boron trifluoride co-condensed with carbon monoxide, sulphur dioxide, ammonia and dimethyl ether in nitrogen and argon matrices have been recorded. The spectra have been analyzed on the basis of the formation of 1:1 complexes between the boron trifluoride and the electron donor molecules, and the wavenumber shifts of the antisymmetric stretching mode of boron trifluoride have been used as probes of the natures and the strengths of the electron donor-acceptor interactions present.

Paper Details

Date Published: 31 January 1994
PDF: 2 pages
Proc. SPIE 2089, 9th International Conference on Fourier Transform Spectroscopy, (31 January 1994); doi: 10.1117/12.166770
Show Author Affiliations
L. M. Nxumalo, Univ. of the Witwatersrand (South Africa)
T. A. Ford, Univ. of Natal (South Africa)


Published in SPIE Proceedings Vol. 2089:
9th International Conference on Fourier Transform Spectroscopy
John E. Bertie; Hal Wieser, Editor(s)

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