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Proceedings Paper

Fourier transform infrared study on microemulsion system of potassium salt of bis(2-ethylhexyl) phosphinic acid (HA)
Author(s): Weijin Zhou; Nai Shi; Yi Wang; Zhiyuan Chang; JinGuang Wu
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Paper Abstract

To study microemulsion formation in a solvent extraction system is to probe into some basic principles of extraction chemistry in the light of combining extraction chemistry with surface chemistry. In our previous investigations, the microemulsions of the salts of HDEHP and PC88A have been studied systematically by FT-IR. In the experiment, we observed the change of peak positions and intensities of P equals O, P-O-C and P-O-H groups during saponification and hydration, and discovered that the peak of P-O-C splits apart into 1045 and 1075 cm-1. The vibration frequency of the P-O-C group in HDEHP and PC88A is quite close to the symmetric stretching frequency of the POO- group, and thus causes difficulties in the study of their peak position and absorbance variation. For this reason we synthesized bis(2-ethylhexyl) phosphinic acid without the P-O-C group. Infrared spectra in the range of 800 - 4000 cm-1 of this microemulsion system was studied.

Paper Details

Date Published: 31 January 1994
PDF: 2 pages
Proc. SPIE 2089, 9th International Conference on Fourier Transform Spectroscopy, (31 January 1994); doi: 10.1117/12.166612
Show Author Affiliations
Weijin Zhou, Peking Univ. (China)
Nai Shi, Peking Univ. (China)
Yi Wang, Peking Univ. (China)
Zhiyuan Chang, Peking Univ. (China)
JinGuang Wu, Peking Univ. (China)


Published in SPIE Proceedings Vol. 2089:
9th International Conference on Fourier Transform Spectroscopy
John E. Bertie; Hal Wieser, Editor(s)

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