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Proceedings Paper

Reflections on the molecular Hamiltonian
Author(s): K. N. Bogatyrev; V. P. Makarov
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Paper Abstract

In this paper we consider the two methods of transformation of the Hamiltonian of poliatomic molecules to arbitrary molecular coordinates. In these coordinates the classical Hamilton function on their form is shown to differ from the quantum mechanical Hamiltonian on the term U ' (q) in accord with Watson's results. The correspondence rule (p yields -in(alpha) /(alpha) R) can be applied for the transformation of the classical Hamilton function only in the Cartesian coordinates to the Hamiltonian of quantum mechanics.

Paper Details

Date Published: 26 January 1994
PDF: 7 pages
Proc. SPIE 2205, 11th Symposium and School on High-Resolution Molecular Spectroscopy, (26 January 1994); doi: 10.1117/12.166206
Show Author Affiliations
K. N. Bogatyrev, General Physics Institute (Russia)
V. P. Makarov, General Physics Institute (Russia)

Published in SPIE Proceedings Vol. 2205:
11th Symposium and School on High-Resolution Molecular Spectroscopy
Alexander I. Nadezhdinskii; Yu V. Ponomarev; Leonid N. Sinitsa, Editor(s)

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