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Proceedings Paper

Molecular constant error propagations into Franck-Condon integrals
Author(s): A. V. Stolyarov; E. A. Pazyuk; I. V. Ushakov; R. S. Ferber
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Paper Abstract

An approximated analytical expression connecting the statistical uncertainties in rotational- vibration molecular constants with variations of Franck-Condon type integrals (FCI) has been obtained by applying a first order perturbation theory to the Morse oscillator model. The FCI dependencies on a presence of rotational-vibration interaction and effect of isotopic substitution have also been found in explicit forms.

Paper Details

Date Published: 26 January 1994
PDF: 5 pages
Proc. SPIE 2205, 11th Symposium and School on High-Resolution Molecular Spectroscopy, (26 January 1994); doi: 10.1117/12.166198
Show Author Affiliations
A. V. Stolyarov, Moscow State Univ. (Russia)
E. A. Pazyuk, Moscow State Univ. (Russia)
I. V. Ushakov, Latvian State Univ. (Latvia)
R. S. Ferber, Latvian State Univ. (Latvia)

Published in SPIE Proceedings Vol. 2205:
11th Symposium and School on High-Resolution Molecular Spectroscopy
Alexander I. Nadezhdinskii; Yu V. Ponomarev; Leonid N. Sinitsa, Editor(s)

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