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Proceedings Paper

Qualitative treatment of configuration degeneration in the vibration-rotational spectrum of a nonrigid molecule
Author(s): Alexander V. Burenin
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Paper Abstract

The configuration degeneration in a vibration-rotational spectrum of a nonrigid molecule is performed using a concept of symmetry group chains of models inserted into each other. The models arise in analytic solution of the problem on stationary states of molecules employing the perturbation theory. An example of the nonrigid molecule NH3 in the nondegenerate vibrational state is considered. It is shown that the configuration degeneration treatment depends essentially on the type of the transition between energetically equivalent equilibrium configuration of the molecule.

Paper Details

Date Published: 26 January 1994
PDF: 5 pages
Proc. SPIE 2205, 11th Symposium and School on High-Resolution Molecular Spectroscopy, (26 January 1994); doi: 10.1117/12.166194
Show Author Affiliations
Alexander V. Burenin, Institute of Applied Physics (Russia)


Published in SPIE Proceedings Vol. 2205:
11th Symposium and School on High-Resolution Molecular Spectroscopy
Alexander I. Nadezhdinskii; Yu V. Ponomarev; Leonid N. Sinitsa, Editor(s)

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