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Proceedings Paper

Laser-desorption mass spectrometry and induced coalescence of fullerenes
Author(s): Chahan X. Yeretzian; Marcos M. Alvarez; Barbara DiCamillo; Robert L. Whetten
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Paper Abstract

This article reviews the evolution of the UCLA fullerene research over the past two years from the perspective of laser desorption mass spectrometry (LDMS). As a fast and sensitive analytical method, it has critically contributed to a wide range of fullerene related research projects. Immediately after the discovery of a method for making C60, C70 and selected higher fullerenes in macroscopic amounts, a concerted effort in different laboratories led to the isolation and structure determination of C76, C78, C82 and tentatively C84. Simultaneously with the work on pure fullerene, important progress was achieved in the synthesis of metallofullerenes and derivatized fullerenes. LDMS continually documented progress or failure in extraction, isolation and synthesis and helped to plan future research. Recently, synthesis of C60 and larger fullerenes from precursors, e.g., C18(CO)6, and coalescence reactions of fullerenes, induced by high fluence of the desorption laser, introduced a new aspect of this otherwise exclusively analytical method.

Paper Details

Date Published: 2 July 1993
PDF: 11 pages
Proc. SPIE 1857, Lasers and Optics for Surface Analysis, (2 July 1993); doi: 10.1117/12.148509
Show Author Affiliations
Chahan X. Yeretzian, Univ. of California/Los Angeles (United States)
Marcos M. Alvarez, Univ. of California/Los Angeles (United States)
Barbara DiCamillo, Univ. of California/Los Angeles (United States)
Robert L. Whetten, Univ. of California/Los Angeles (United States)

Published in SPIE Proceedings Vol. 1857:
Lasers and Optics for Surface Analysis
Mattanjah S. de Vries, Editor(s)

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