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Proceedings Paper

Laser spectroscopy of chemically reactive species
Author(s): Ming T. Wu; Trevor J. Sears
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Paper Abstract

We report the observation of stimulated emission pumping spectra in the NCO radical formed in a supersonic free jet expansion by the reaction between photolytically generated CN radicals and O2. The spectra give rotationally resolved information on high lying vibrational levels that are difficult or impossible to detect by conventional single photon spectroscopic techniques. These new data provide detailed insight into the Renner-Teller, spin-orbit and Fermi-resonance coupling in the molecule. They also provide a solid basis for future state- selected chemical and dynamical studies involving this important radical species.

Paper Details

Date Published: 22 April 1993
PDF: 10 pages
Proc. SPIE 1858, Laser Techniques for State-Selected and State-to-State Chemistry, (22 April 1993); doi: 10.1117/12.143116
Show Author Affiliations
Ming T. Wu, Brookhaven National Lab. (United States)
Trevor J. Sears, Brookhaven National Lab. (United States)


Published in SPIE Proceedings Vol. 1858:
Laser Techniques for State-Selected and State-to-State Chemistry
Cheuk Yiu Ng, Editor(s)

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