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Proceedings Paper

Resonance flourescence examination of the allyl radical B[12A1] and C[22B1] excited states
Author(s): James D. Getty; Xianming Liu; Peter B. Kelly
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Paper Abstract

The B[12A1] and C[22B1] electronic states of the allyl radical have been examined by laser spectroscopy. The spectra are classified according to the theory of resonance secondary radiation as predominantly resonance fluorescence in the excitation wavelength range from 242 nm to 250 nm. The observed emission spectra are indicative of the vibronic nature of the absorption bands. The excited state vibrational frequencies for (nu) 7 and (nu) 12 of the C[22B1] state are found to be 375 cm-1 and 509 cm-1.

Paper Details

Date Published: 22 April 1993
PDF: 10 pages
Proc. SPIE 1858, Laser Techniques for State-Selected and State-to-State Chemistry, (22 April 1993); doi: 10.1117/12.143104
Show Author Affiliations
James D. Getty, Univ. of California/Davis (United States)
Xianming Liu, Univ. of California/Davis (United States)
Peter B. Kelly, Univ. of California/Davis (United States)


Published in SPIE Proceedings Vol. 1858:
Laser Techniques for State-Selected and State-to-State Chemistry
Cheuk Yiu Ng, Editor(s)

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