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Proceedings Paper

Application of ion imaging to the study of unimolecular and bimolecular reactions
Author(s): Theo Kitsopoulos; Mark A. Buntine; David P. Baldwin; Richard N. Zare; David W. Chandler
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Paper Abstract

We use the photofragment ion imaging technique to investigate the 266 nm photodissociation dynamics of hydrogen iodide. We show the quantitative features of ion imaging by comparing determinations of photofragment recoil velocity distributions, product branching ratios and the HI bond dissociation energy with previously published results. Excellent agreement with previous experimental and theoretical results is obtained. The H atoms produced from this process are then used as reactants in the reaction of H + HI and H + D2. Imaging techniques are used to measure the velocity distributions of the products of these reactions.

Paper Details

Date Published: 22 April 1993
PDF: 13 pages
Proc. SPIE 1858, Laser Techniques for State-Selected and State-to-State Chemistry, (22 April 1993); doi: 10.1117/12.143074
Show Author Affiliations
Theo Kitsopoulos, Sandia National Labs. (United States)
Mark A. Buntine, Yale Univ. (United States)
David P. Baldwin, Ames Lab/Iowa State Univ. (United States)
Richard N. Zare, Stanford Univ. (United States)
David W. Chandler, Sandia National Labs. (United States)


Published in SPIE Proceedings Vol. 1858:
Laser Techniques for State-Selected and State-to-State Chemistry
Cheuk Yiu Ng, Editor(s)

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