We have measured bound exciton luminescences from PbI₂ microcrystallites in the shape of a platelet embedded into E-MAA copolymer at 4.2 K. An energy shift of the bound exciton from the free exciton increases as the thickness of the crystallite decrease, and amounts to 51 meV in the crystallite with a monolayer, which is about seven times as large as that of the bulk crystal. This fact strongly suggests that the binding energy of the free exciton becomes larger both for the size confinement and dielectric screening effects.

Date Published: 3 September 1992
PDF: 6 pages
Proc. SPIE 1675, Quantum Well and Superlattice Physics IV, (3 September 1992); doi: 10.1117/12.137587

Published in SPIE Proceedings Vol. 1675:
Quantum Well and Superlattice Physics IV